Intramolecular Methylation of an Allyl Sulfone via Lithium Alkoxyaluminate; Application to the Enantioselective Synthesis of the CD Ring of Vitamin D3
收藏Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Intramolecular_Methylation_of_an_Allyl_Sulfone_via_Lithium_Alkoxyaluminate_Application_to_the_Enantioselective_Synthesis_of_the_CD_Ring_of_Vitamin_D_sub_3_sub_/2518141
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Alcohol-directed intramolecular methylation of an enantiopure allyl sulfone using AlMe3 provides a trans-hydrindane CD ring alcohol. The substrate cis-CD ring allyl sulfone alcohol is prepared via intramolecular allyl sulfonyl anion addition to aldehyde using Ba(OH)2.
创建时间：
2016-02-20
