High-Nuclear Vanadoniobate {Nb48V8} Multiple-Strand Wheel
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资源简介：
An unprecedented octavanadium-substituted polyoxoniobate Na18[Nb48V8(OH)30O130]·33H2O (1), with a multiple-strand wheel structure, was successfully synthesized via a conventional aqueous method, which represents the largest vanadoniobate cluster reported to date. Single-crystal X-ray diffraction, ESI-MS spectrum, IR spectra, and UV–vis spectra were investigated. In addition, photocatalytic H2 evolution activity for 1 under UV light was observed with TEA as a sacrificial electron donor.
创建时间：
2016-02-12
