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A Zirconium (1-Pyridinio)imido Complex: Facile N−N Bond Cleavage and N−C Bond Formation

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NIAID Data Ecosystem2026-03-06 收录
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Reaction of a (1-pyridinio)imidozirconium complex with isocyanides or CO leads to instantaneous N−N bond cleavage and the concomitant formation of the carbodiimido complexes [Zr(N2TBSNpy](NCNR)(OTf)(py)] or the isocyanato complex [Zr(N2TBSNpy](NCO)(OTf)(py)], respectively.

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2016-02-27
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