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A Germanium(II)-Centered Dication

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/A_Germanium_II_Centered_Dication/2969332
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The dicationic 42+ complex with three N-heterocyclic carbenes coordinated to a germanium center is reported. The complex was characterized by 1H NMR and FT Raman spectroscopy, and the structure was determined by single-crystal X-ray diffraction. Electronic structure calculations reveal a partial positive charge at germanium and that the germanium lone pair shows no evidence for π bonding.
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2016-02-27
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