Investigation of the concentration- and temperature-dependent motion of colloidal nanoparticles

Although the motion of a single nanoparticle suspended in a fluid can be easily modeled, things get complicated for non-infinitely diluted systems. Coincidentally, these are the systems of interest in relevant fields such as, nanomedicine, microfluidics and miniaturized energy storage devices. Hence, a better understanding of the dynamics of colloidal nanoparticles is utterly needed. Herein, the motion of colloidal suspension of plasmonic nanoparticles (<em>i.e.</em>, gold nanoshells) is investigated <em>via</em> laser speckle imaging. The method relies on the analysis of the speckle pattern generated by colloidal suspensions forced to flow at specific velocities. Temperature-dependent measurements corroborated that the dynamics of non-infinitely diluted nanoparticle suspensions are better described through a diffusive model rather than by the equipartition theorem. Under the tested experimental conditions, an average diffusion velocity between 0.37 and 1.57 mm s⁻¹ was found. Most importantly, these values were largely dependent on the nanoparticle concentration. These results are in agreement with previous reports and indicate the existence of long-range interactions between nanoparticles.