Tandem Oxidative Dearomatization/Intramolecular Diels–Alder Reaction for Construction of the Tricyclic Core of Palhinine A
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https://figshare.com/articles/dataset/Tandem_Oxidative_Dearomatization_Intramolecular_Diels_Alder_Reaction_for_Construction_of_the_Tricyclic_Core_of_Palhinine_A/2525482
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A concise construction of the 6/6/5 tricyclic core of Lycopodium alkaloid palhinine A (1) has been accomplished. The developed synthetic strategy featured a tandem oxidative dearomatization/intramolecular Diels–Alder reaction to construct C/D rings and an intramolecular 5-exo-trig radical cyclization to install the B ring of palhinine A (1). The developed approach paves the way for the total synthesis of palhinine A (1).
创建时间：
2016-02-21
