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Molecular Fabric Structure Formed by the 1D Coordination Polymer, [Pb(bpe)(O<sub>2</sub>CCH<sub>3</sub>)(O<sub>2</sub>CCF<sub>3</sub>)]

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Crystallization of trans-1,2-bis(4-pyridyl)ethylene (bpe) with PbII acetate in the presence of CF3COOH yielded [Pb(bpe)(O2CCH3)(O2CCF3)]n, and the solid-state structure contains spiral 1D coordination polymers entangled in a “warp and weft” interwoven structure. The absence of any weak interactions between the tangled strands in the 2D sheets make this a true molecular fabric structure.

创建时间:
2016-02-27
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