4-Cyanoimidazolate: A New Pseudo-Cyanide?
收藏NIAID Data Ecosystem2026-03-06 收录
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Because of its exobidentate nature, pKa, and electronic properties, 4-cyanoimidazole has been examined as a ligand and as a pseudo-cyanide. The ligand reacts readily as an anion with both cobalt and nickel ions in solution to form coordination polymers. The magnetic susceptibility and thermal stability of these materials are reported. 4-Cyanoimidazolate forms a hexakis complex with nickel, to form the first observed hexakis imidazolate nickelate complex.
创建时间：
2016-05-06
