The First Structurally Authenticated Rb−PR<sub>3</sub> and Cs−PR<sub>3</sub> Contacts. Synthesis and Crystal Structures of [Rb{(Me<sub>3</sub>Si)<sub>2</sub>CP(C<sub>6</sub>H<sub>4</sub>-2-CH<sub>2</sub>NMe<sub>2</sub>)<sub>2</sub>}]<i><sub>n</sub></i> and [Cs{(Me<sub>3</sub>Si)<sub>2</sub>CP(C<sub>6</sub>H<sub>4</sub>-2-CH<sub>2</sub>NMe<sub>2</sub>)<sub>2</sub>}(toluene)]<i><sub>n</sub></i>
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
https://figshare.com/articles/dataset/The_First_Structurally_Authenticated_Rb_PR_sub_3_sub_and_Cs_PR_sub_3_sub_Contacts_Synthesis_and_Crystal_Structures_of_Rb_Me_sub_3_sub_Si_sub_2_sub_CP_C_sub_6_sub_H_sub_4_sub_-2-CH_sub_2_sub_NMe_sub_2_sub_sub_2_sub_i_sub_n_sub_i_and_Cs_Me_sub_3_sub_Si_sub_/3764574数据链接链接失效反馈
官方服务：
资源简介：
Metathesis between [Li{([Me3Si]2C)P(C6H4-2-CH2NMe2)2}] (1) and either RbOR or CsOR (R = 2-ethylhexyl) gives the heavier alkali metal phosphinomethanide complexes [Rb{([Me3Si]2C)P(C6H4-2-CH2NMe2)2}]n (4) and [Cs{([Me3Si]2C)P(C6H4-2-CH2NMe2)2}(toluene)]n (5), respectively, after recrystallization. Compounds 4 and 5 represent the first examples of complexes containing a Rb−PR3 or Cs−PR3 bond.
创建时间：
2016-08-26
