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Elucidation of Tetraboric Acid with a New Borate Fundamental Building Block in a Chiral Uranyl Fluoroborate

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Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Elucidation_of_Tetraboric_Acid_with_a_New_Borate_Fundamental_Building_Block_in_a_Chiral_Uranyl_Fluoroborate/2472256
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A new neutral borate species, H2B4O7 (also known as tetraboric acid), with a one-dimensional chain structure, is found in the interlayer spacing in Rb2[(UO2)2B8O12F6]·H2B4O7 (RbUBOF-2) derived from boric acid flux reaction of uranyl­(VI) nitrate with RbBF4. This new form of tetraboric acid possesses a novel borate fundamental building block with the symbol 4Δ:⟨3Δ⟩Δ.
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2016-02-20
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