Selective Preparation of Diamondoid Phosphonates
收藏Figshare2016-02-17 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Selective_Preparation_of_Diamondoid_Phosphonates/2285443
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We present an effective sequence for the preparation of phosphonic acid derivatives of the diamondoids diamantane, triamantane, [121]tetramantane, and [1(2,3)4]pentamantane. The reactions of the corresponding diamondoid hydroxy derivatives with PCl3 in sulfuric or trifluoroacetic acid give mono- as well as didichlorophosphorylated diamondoids in high preparative yields.
创建时间:
2016-02-17



