Double C−H Activation in a Rh−NHC Complex Leading to the Isolation of a 14-Electron Rh(III) Complex
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https://figshare.com/articles/dataset/Double_C_H_Activation_in_a_Rh_NHC_Complex_Leading_to_the_Isolation_of_a_14_Electron_Rh_III_Complex/3375388
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资源简介:
The solvent-dependent interaction of ItBu with a Rh(I)−olefin complex leads to the isolation of two precursors en route to a unique double cyclometalation process. Abstraction of the chloride ligand from the resulting complex enables the isolation of a “bare” 14-electron Rh(III) complex.
创建时间:
2016-05-12



