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Double C−H Activation in a Rh−NHC Complex Leading to the Isolation of a 14-Electron Rh(III) Complex

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NIAID Data Ecosystem2026-03-06 收录
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The solvent-dependent interaction of ItBu with a Rh(I)−olefin complex leads to the isolation of two precursors en route to a unique double cyclometalation process. Abstraction of the chloride ligand from the resulting complex enables the isolation of a “bare” 14-electron Rh(III) complex.

创建时间:
2016-05-12
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