Access to the Phosphorylindenopyrazole Scaffold via a Metal-Free Domino Reaction of Diazoalkylphosphonates with 3‑Bromophthalides
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https://figshare.com/articles/dataset/Access_to_the_Phosphorylindenopyrazole_Scaffold_via_a_Metal-Free_Domino_Reaction_of_Diazoalkylphosphonates_with_3_Bromophthalides/4055166
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资源简介：
A novel strategy
is reported here for the synthesis of an indenopyrazole
scaffold bearing a phosphonate group. The entire sequence includes
nucleophilic addition–elimination, Seyferth–Gilbert
homologation, transphosphorylation, and a 1,3-dipolar cycloaddition
reaction of diazoalkylphosphonates in a perfect “domino”
manner.
创建时间：
2016-11-14
