An Isolable Bis-Silylene Oxide (“Disilylenoxane”) and Its Metal Coordination
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
The first isolable oxygen-bridged bis-silylene 1 has been synthesized by facile dehydrochloration of the corresponding disiloxane [LSiH(Cl)−O−SiH(Cl)L] precursor [L = PhC(NtBu)2] with LiN(SiMe3)2. Compound 1 contains three-coordinate, pyramidal Si(II) atoms in a bent disiloxane-like moiety and reacts readily with [Ni(COD)2] to afford the unique bis-silylene oxide nickel complex 3.
创建时间：
2016-02-24
