A New Class of Azadipnictiridines Generated by an Unusual Rearrangement Reaction
收藏Figshare2016-02-16 更新2026-04-29 收录
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https://figshare.com/articles/dataset/A_New_Class_of_Azadipnictiridines_Generated_by_an_Unusual_Rearrangement_Reaction/2240287
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资源简介：
Dipnictadiazanediyls, [E(μ-NR)]2 (E = P, As), the pnictogen analogues of cyclobutandiyl, were found to react readily with alkynes forming [2.1.1]bicyclic structures. These, in turn, rearrange in an unprecedented reaction to [3.1.o]bicycles leading to the isolation of the first azadiarsiridine and the determination of its solid-state structure. All new species were comprehensively characterized, and the reaction pathways and bonding situations were computationally studied.
创建时间：
2016-02-16
