Dibenzylstrontium and -barium: Simple Molecules with Complex Structures
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https://figshare.com/articles/dataset/Dibenzylstrontium_and_barium_Simple_Molecules_with_Complex_Structures/2156179
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资源简介：
The
reactions between two equivalents of PhCH2K and
AeI2 (Ae = Ca, Sr, Ba) in THF give the alkaline earth metal
benzyls [(PhCH2)2Ca(THF)4]
(3), [(PhCH2)4Sr2(THF)3] (4), and [(PhCH2)6Ba3(THF)4] (5), as
orange, crystalline solids in good yield. While 3 crystallizes
as a molecular species, compound 4 crystallizes as a
ribbon polymer and 5 crystallizes as a 2-dimensional
sheet in which the metal ions are coordinated by either benzyl and
THF molecules or benzyl ligands alone.
创建时间：
2016-02-13
