Lewis Base-Promoted Rearrangement of Allylic Cyanohydrins: Construction of Functionalized Nitriles Bearing 1,3-Diketone Moieties
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https://figshare.com/articles/dataset/Lewis_Base_Promoted_Rearrangement_of_Allylic_Cyanohydrins_Construction_of_Functionalized_Nitriles_Bearing_1_3_Diketone_Moieties/2232823
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资源简介:
A novel
Lewis base-promoted rearrangement of allylic cyanohydrins
has been developed, in which the cyano group was rearranged, directly
coupled with the generation of new functional groups. This protocol
provides a unique and facile way to prepare highly functionalized
nitriles bearing 1,3-diketone moieties under mild reaction conditions.
Furthermore, the synthetic transformations of the functionalized products
have also been demonstrated.
创建时间:
2014-11-21



