Stereocontrolled Synthesis of (−)-Kainic Acid from <i>trans-</i>4-Hydroxy-l-proline<sup>†</sup>
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A highly stereoselective synthesis of (−)-kainic acid has been achieved in 14 steps and >7% overall yield starting from inexpensive trans-4-hydroxy-l-proline. The key steps are diastereoselective enolate alkylation and cuprate substitution reactions.
创建时间：
2016-05-05
