Two Novel Thioindate-Thioantimonate Compounds [Ni(dien)<sub>2</sub>]<sub>2</sub>In<sub>2</sub>Sb<sub>4</sub>S<sub>11</sub> and [Ni(dien)<sub>2</sub>]<sub>3</sub>(In<sub>3</sub>Sb<sub>2</sub>S<sub>9</sub>)<sub>2</sub>·2H<sub>2</sub>O with Transition Metal Complexes
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Two novel thioindate-thioantimonate compounds [Ni(dien)2]2In2Sb4S11 (1) and [Ni(dien)2]3(In3Sb2S9)2·2H2O (2) (dien = diethylenetriamine) have been solvothermally synthesized and structurally characterized. 1 contains heterometallic pseudosemicube [In2SbS8] clusters and bow-like trimeric [Sb3S7] units, which are linked to form a [In2Sb4S114−]n chain, whereas 2 consists of chain-like [In6S18] units and pyramidal SbS3, which are interconnected to give a [In3Sb2S96−]n layer with a large rectangle-like 12-ring. The optical properties of 1 and 2 have been investigated by UV−vis spectroscopy.
创建时间：
2010-10-18
