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Alkyl Complexes of Strontium and Barium: Synthesis and Structural Characterization of {(Me<sub>3</sub>Si)<sub>2</sub>(MeOMe<sub>2</sub>Si)C}<sub>2</sub>Sr(THF) and {(Me<sub>3</sub>Si)<sub>2</sub>(MeOMe<sub>2</sub>Si)C}<sub>2</sub>Ba(MeOCH<sub>2</sub>CH<sub>2</sub>OMe)

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Metathesis between either SrI2 or BaI2 and 2 equiv of {(Me3Si)2(MeOMe2Si)C}K in THF yields the novel heavier alkali metal dialkyls {(Me3Si)2(MeOMe2Si)C}2M(L) [M(L) = Sr(THF) (2), Ba(DME) (3) (DME = 1,2-dimethoxyethane)] after recrystallization.

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2016-08-18
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