官方服务:
资源简介:
U and Pu trivalent Cp complexes; contrasting small molecule activation using metal or Cp as redox source
应用场景:
创建时间:
2026-03-16
相关数据集
Insertion of Isonitriles into the M–C Bonds of Group 4 Dialkyl Complexes
The 2,3-dimethylbutadiene complexes of Group 4 metals with constrained geometry (cg) ligands have been prepared and found to adopt a supine orientation with σ2,π bonding. Treatment of cgTi(2,3-dimet
NIAID Data Ecosystem60
Synthesis, Structure, and Bridge-Terminal Exchange Kinetics of Pyrazolate-Bridged Digallium and Diindium Complexes Containing Bridging Phenyl Groups
Treatment of triphenylgallium with 3,5-dimethylpyrazole, 3,5-diphenylpyrazole, or 3,5-di-tert-butylpyrazole in a 2:1 stoichiometry afforded the phenyl-bridged complexes (C6H5)2Ga(μ-Me2pz)(μ-C6H5)Ga(C6
NIAID Data Ecosystem40
Activation of Molecular Oxygen by a Molybdenum(IV) Imido Compound
Activation of molecular dioxygen at a molybdenum(IV) imido compound led to the isolation and full characterization of a remarkably stable transition-metal imidoperoxido complex.
NIAID Data Ecosystem30
Structural and Spectroscopic Studies of the PCP-Bridged Heavy Chalcogen-Centered Monoanions [HC(PPh 2 E)(PPh 2 )] − (E = Se, Te) and [HC(PR 2 E) 2 ] − (E = Se, Te, R = Ph; E = Se, R = i Pr): Homoleptic Group 12 Complexes and O
Selenium- and tellurium-containing bis(diphenylphosphinoyl)methane monoanions were prepared by oxidation of the anion [HC(PPh2)2]− with elemental chalcogens. The selenium-containing isopropyl derivati
NIAID Data Ecosystem40
Formation of Acene-Based Polymers: Mechanistic Computational Study
Understanding the mechanism of linear acene decomposition and its reactivity is a prerequisite for controlling the stability of acenes and their future applications. Previously, we suggested that long
Figshare2016-02-18 更新30



