C–P or C–H Bond Cleavage of Phosphine Oxides Mediated by an Yttrium Hydride
收藏NIAID Data Ecosystem2026-03-07 收录
下载链接：
https://figshare.com/articles/dataset/C_P_or_C_H_Bond_Cleavage_of_Phosphine_Oxides_Mediated_by_an_Yttrium_Hydride/2511370
下载链接
链接失效反馈官方服务：
资源简介：
Reactions of the yttrium anilido hydride [LY(NH(DIPP))(μ-H)]2 (1; L = [MeC(N(DIPP))CHC(Me)(NCH2CH2NMe2)]−, DIPP = 2,6-iPr2C6H3)) with three phosphine
oxides and two phosphine sulfides are reported. The reaction of 1 with Ph3PO gives C–P bond cleavage
and an yttrium anilido phosphinoyl complex, while those with R2MePO (R = Me, Ph) result in C–H bond cleavage
and two yttrium anilido alkyl complexes. 1 also reacted
with R3PS (R = Me, Ph), which demonstrated P–S
bond cleavage via hydride-based reduction and gave an yttrium anilido
sulfide.
创建时间：
2012-06-25
