C–H Phosphonation of Pyrrolopyrimidines: Synthesis of Substituted 7- and 9‑Deazapurine-8-phosphonate Derivatives
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https://figshare.com/articles/dataset/C_H_Phosphonation_of_Pyrrolopyrimidines_Synthesis_of_Substituted_7-_and_9_Deazapurine-8-phosphonate_Derivatives/3969177
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资源简介：
The Mn(OAc)3-promoted C–H phosphonation of 7-deazapurines
(pyrrolo[2,3-d]pyrimidines) and 9-deazapurines (pyrrolo[3,2-d]pyrimidines) with diethylphosphite was developed. The
reactions occur regioselectively at position 8 both in 7 and 9-deazapurines,
leading to new deazapurine-8-phosphonate derivatives, which can be
further modified and transformed to 6-(het)aryl-deazapurine derivatives
or deprotected to free phosphonic acids.
创建时间：
2016-10-03
