Synthesis and Structural Characterization of Carborane-Containing Neutral, Self-Assembled Pt-Metallacycles
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Synthesis_and_Structural_Characterization_of_Carborane_Containing_Neutral_Self_Assembled_Pt_Metallacycles/3252694
下载链接
链接失效反馈官方服务：
资源简介：
We have combined carborane chemistry with the newly developed directional bonding strategy to
synthesize neutral macrocycles. The m- and p-carborane dicarboxylates were utilized as the donor
linkers in conjunction with 1,8-bis[trans-Pt(PEt3)2NO3]anthracene 3, 2,9-bis[trans-Pt(PEt3)2NO3]phenanthrene 5, and cis-Pt(PEt3)2(NO3)2 unit 6. Three new platinum-based macrocycles, 4, 7, and
8, were thus synthesized. 31P{1H} NMR as well as the X-ray characterization of Pt-metallacycles
reveal the formation of single highly symmetrical neutral species.
创建时间：
2016-05-05
