An Isolable Magnesium(II)-Radical Dianion Complex
收藏NIAID Data Ecosystem2026-03-13 收录
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https://figshare.com/articles/dataset/An_Isolable_Magnesium_II_-Radical_Dianion_Complex/16783437
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资源简介：
Magnesium(I) complexes have attracted
a great deal of attention
because of their practical application as elegant organic-soluble
reducing agents in small-molecule activation and organometallic synthesis.
However, no stable mononuclear magnesium(I) compounds have been isolated
so far. Herein, we used the ligand 3,6-di-tert-butyl-1,8-bis(10-phenylanthracen-9-yl)carbazolyl
(L–) to synthesize the magnesium(I) species, and
the magnesium complex LMg(THF)2 (3) was isolated.
Electron paramagnetic resonance spectroscopic studies and theoretical
calculations reveal that the unpaired electron mainly resides at one
of the anthracenyl moieties, and 3 is essentially a magnesium(II)-radical
dianion complex.
创建时间：
2021-10-11
