Field-Induced Slow Magnetic Relaxation in a Six-Coordinate Mononuclear Cobalt(II) Complex with a Positive Anisotropy
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https://figshare.com/articles/dataset/Field_Induced_Slow_Magnetic_Relaxation_in_a_Six_Coordinate_Mononuclear_Cobalt_II_Complex_with_a_Positive_Anisotropy/2483386
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资源简介：
The novel mononuclear Co(II) complex cis-[CoII(dmphen)2(NCS)2]·0.25EtOH
(1) (dmphen = 2,9-dimethyl-1,10-phenanthroline) features
a
highly rhombically distorted octahedral environment that is responsible
for the strong positive axial and rhombic magnetic anisotropy of the
high-spin CoII ion (D = +98 cm–1 and E = +8.4 cm–1). Slow magnetic
relaxation effects were observed for 1 in the presence
of a dc magnetic field, constituting the first example of field-induced
single-molecule magnet behavior in a mononuclear six-coordinate Co(II)
complex with a transverse anisotropy energy barrier.
创建时间：
2012-09-26
