Calix[4]arenes with Two Different Chemical Modifications at the Bridges
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https://figshare.com/articles/dataset/Calix_4_arenes_with_Two_Different_Chemical_Modifications_at_the_Bridges/2650465
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资源简介：
Hexabromocalix[4]arene derivatives (3a and 3b) possessing pairs of dibromomethylene and bromomethylene groups located at distal or proximal positions of the calix scaffold were prepared via photochemical bromination of tetramethoxycalix[4]arene. The dibromomethylene groups undergo hydrolysis to afford calix[4]arenes possessing pairs of carbonyl groups and bromomethylene groups located at distal or proximal bridges (4a and 4b, respectively). The bromomethylene groups of 4 undergo reactions with nucleophiles under SN1 conditions to afford a wide array of derivatives possessing two different chemical modifications at the bridges.
创建时间：
2011-05-20
