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Highly Syndiospecific Polymerization of Styrene Catalyzed by Allyl Lanthanide Complexes

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https://figshare.com/articles/dataset/Highly_Syndiospecific_Polymerization_of_Styrene_Catalyzed_by_Allyl_Lanthanide_Complexes/3321922
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Allylic complexes of lanthanides bearing a fluorenyl-based ligand are active single-component catalysts for the polymerization of styrene, giving highly syndiotactic polymers (rrrr > 99%) with low to high molecular weight (Mn = 8000−135 000) and narrow polydispersities (Mw/Mn = 1.25−2.1).
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2016-05-06
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