C^C* Platinum(II) Complexes with Electron-Withdrawing Groups and Beneficial Auxiliary Ligands: Efficient Blue Phosphorescent Emission
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https://figshare.com/articles/dataset/C_C_Platinum_II_Complexes_with_Electron-Withdrawing_Groups_and_Beneficial_Auxiliary_Ligands_Efficient_Blue_Phosphorescent_Emission/14944367
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资源简介:
The combination of
strong electron-withdrawing groups in cyclometalated
N-heterocyclic carbene ligands (C^C*) with known beneficial auxiliary
ligands in phosphorescent platinum(II) complexes leads to efficient
light-to-deep-blue emission with quantum yields of up to 92%. All
compounds were characterized and investigated regarding their photophysical,
electrochemical, and thermal properties, and three complexes could
additionally be characterized by solid-state structures. Density functional
theory calculations (PBE0/6-311G* with dispersion correction) are
reported.
创建时间:
2021-07-09



