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C^C* Platinum(II) Complexes with Electron-Withdrawing Groups and Beneficial Auxiliary Ligands: Efficient Blue Phosphorescent Emission

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NIAID Data Ecosystem2026-03-12 收录
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The combination of strong electron-withdrawing groups in cyclometalated N-heterocyclic carbene ligands (C^C*) with known beneficial auxiliary ligands in phosphorescent platinum­(II) complexes leads to efficient light-to-deep-blue emission with quantum yields of up to 92%. All compounds were characterized and investigated regarding their photophysical, electrochemical, and thermal properties, and three complexes could additionally be characterized by solid-state structures. Density functional theory calculations (PBE0/6-311G* with dispersion correction) are reported.

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2021-07-09
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