Synthesis of α‑Aminophosphonates via Phosphonylation of an Aryne–Imine Adduct
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https://figshare.com/articles/dataset/Synthesis_of_Aminophosphonates_via_Phosphonylation_of_an_Aryne_Imine_Adduct/12994467
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资源简介：
Multicomponent phosphonylation
is accomplished upon the reaction
of an imine with an aryne generated in situ in the presence of a dialkyl
phosphite. This transition-metal-free protocol shows a broad substrate
scope, providing a variety of α-aminophosphonates in moderate
to good yields. A plausible mechanism for the reaction is proposed
based on a deuterium exchange experiment.
创建时间：
2020-09-14
