Synthesis of α‑Aminophosphonates via Phosphonylation of an Aryne–Imine Adduct
收藏NIAID Data Ecosystem2026-03-12 收录
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Multicomponent phosphonylation is accomplished upon the reaction of an imine with an aryne generated in situ in the presence of a dialkyl phosphite. This transition-metal-free protocol shows a broad substrate scope, providing a variety of α-aminophosphonates in moderate to good yields. A plausible mechanism for the reaction is proposed based on a deuterium exchange experiment.
创建时间：
2020-09-14
