Self-Assembly of an Imidazolate-Bridged FeIII/CuII Heterometallic Cage
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https://figshare.com/articles/dataset/Self_Assembly_of_an_Imidazolate_Bridged_Fe_sup_III_sup_Cu_sup_II_sup_Heterometallic_Cage/2330785
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A rare, discrete, mixed-valent, heterometallic Fe(III)/Cu(II) cage, [Cu6Fe8L8](ClO4)12·χsolvent (H3L = tris{[2-{(imidazole-4-yl)methylidene}amino]ethyl}amine), was designed and synthesized via metal-ion-directed self-assembly with neutral tripodal metalloligands. The formation of this coordination cage was demonstrated by X-ray crystallography, ESI mass spectrometry, FT-IR, and UV–vis-NIR spectroscopy.
创建时间:
2016-02-18



