Cage Shrinkage of Fullerene via a C2 Loss: from IPR C90(28)Cl24 to Nonclassical, Heptagon-Containing C88Cl22/24
收藏Figshare2016-02-18 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Cage_Shrinkage_of_Fullerene_via_a_C_sub_2_sub_Loss_from_IPR_C_sub_90_sub_28_Cl_sub_24_sub_to_Nonclassical_Heptagon_Containing_C_sub_88_sub_Cl_sub_22_24_sub_/2341834
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资源简介：
A new case of chlorination-promoted fullerene cage shrinkage is reported. Chlorination of C90 (isolated pentagon rule isomer no. 28) with VCl4 afforded C88Cl22 with a nonclassic carbon cage (NCC) containing 1 heptagon and 13 pentagons including 2 fused pairs flanking the heptagon. The pathway of C2 abstraction from the C90 cage is suggested on the basis of density functional theory calculations.
创建时间：
2016-02-18
