Diastereoselective and Enantioselective Desymmetrization of α‑Substituted Cyclohexadienones via Intramolecular Stetter Reaction
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https://figshare.com/articles/dataset/Diastereoselective_and_Enantioselective_Desymmetrization_of_Substituted_Cyclohexadienones_via_Intramolecular_Stetter_Reaction/2462362
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资源简介：
Highly diastereoselective and enantioselective desymmetrization
of α-substituted cyclohexadienones via NHC-catalyzed intramolecular
Stetter reaction was realized. Amino-indanol derived triazolium salt
bearing a C6F5 group was found to be the optimal
catalyst precursor in the intramolecular Stetter reaction furnishing
tricyclic products bearing multi-stereocenters in up to 96% yield
and >99% ee.
创建时间：
2012-12-07
