Formation of Indanone from an Iridanaphthalene Complex
收藏Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Formation_of_Indanone_from_an_Iridanaphthalene_Complex/2388955
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资源简介：
The first example of evolution of an iridanaphthalene into an indanone through an intermediate indenyl is reported, serving as a good example of starting material to obtain indanones. Two new iridanaphthalenes are obtained by intramolecular C–H activation of a phenyl ring of a carbene ligand in [IrCp*{C(OMe)CHCPh2}(L)]PF6 (L = PPh2Me, PMe3) complexes. It is demonstrated that these iridanaphthalene complexes can undergo a thermal reaction to give indenyl complexes and 3-phenylindanone.
创建时间：
2016-02-19
