Cr[CH(SiMe3)2]3/SiO2 catalysts for ethene polymerization: the correlation at amolecular level between the chromium loading and the microstructure of the produced polymer

Data type: Experimental spectroscopic measurements, Computer Simulation and Analysis

Files are in txt, spc, par, opj, and m format

Information on origin of the data:

EPR spectroscopic measurements in spc and par formats

EPR spectroscopic simulation and analyses in m format

UV-vis and IR spectroscopic measurements and analyses; and polymer analyses in opj format

Are the data generated (e.g. by a machine) or collected (e.g. by means of a survey)?

EPR spectroscopic measurements were generated by ELEXYS 580 EPR spectrophotometer equipped with SHQ cavity and ER035 M NMR gaussmeter produced by Bruker.

FT-IR spectroscopic measurements were generated by Vertex70 produced by Bruker equipped with an MCT detector.

UV-Vis-NIR spectroscopic measurements were generated by Cary5000 spectrophotometer produced by Varian equipped with a reflectance sphere.

If t

Files in PARACAT_WP4_20201229_01_EPR folder includes EPR spectroscopic measurements and computer simulations/analyses, original data are in spc/par formats; files in m format were used to process the data of the same name and saved the results in txt format.

Information on:

specialized abbreviations: EPR – Electron Paramagnetic Resonance, GC – Gas Chromatography, GPC – Gel Permeation Chromatography

definitions of variables: Magnetic field, Wavenumber, Pressure

units of measurement: Gauss (G), milli Tesla (mT), cm-1, milli bar (mbar)

abbreviations: IR/EPR/UV are data relate to measurements of IR/EPR/UV-Vis spectroscopy.

abbreviation: CO/C2H4 are data relate to methods with CO/ethene dosage.

abbreviation: polym is data relates to polymer analysis conducted by GC and GPC