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Synergistic Au/Ga Catalysis in Ambient Nakamura Reaction

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https://figshare.com/articles/dataset/Synergistic_Au_Ga_Catalysis_in_Ambient_Nakamura_Reaction/2336740
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The gold-catalyzed intermolecular addition of 1,3-dicarbonyl compounds to unactivated 1-alkynes (Nakamura reaction) is achieved at room temperature for the first time through synergistic gold/gallium catalysis. The developed system is highly efficient with a gold catalyst loading that can be as low as 500 ppm.
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2016-02-18
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