Crystallographic Structure Determination of Both [5,6]- and [6,6]-Isomers of Lithium-Ion-Containing Diphenylmethano[60]fullerene

Organic
functionalization of lithium-ion-containing [60]­fullerene,
Li+@C60, was performed by using diphenyl­(diazo)­methane
as a stable, readily available diazo compound to obtain lithium-ion-containing
[5,6]- and [6,6]-diphenylmethano[60]­fullerenes, Li+@C61Ph2. The bis­(trifluoromethanesulfonyl)­imide (TFSI)
salts of [5,6]- and [6,6]-Li+@C61Ph2 were successfully separated by using a cation exchange column with
eluent containing LiTFSI. Improved separation protocol and high crystallinity
of ionic components in less polar solvents enabled separate crystallization
of each isomer. Both [5,6]-open and [6,6]-closed structures of Li+@C61Ph2 were determined by synchrotron
radiation X-ray crystallography. Elucidating the [5,6]-open methano[60]­fullerene
(fulleroid) structure will contribute to materials research on fulleroids.