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Synthesis and Lewis Acidity of Fluorinated Triaryl Borates: data

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Figshare2023-01-26 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Synthesis_and_Lewis_Acidity_of_Fluorinated_Triaryl_Borates_data/27277479
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A series of fluorinated triaryl borates B(OArF)3 (ArF = 2-FC6H4, 3-FC6H4, 4-FC6H4, 2,4-F2C6H3, 3,5-F2C6H3, 2,3,4-F3C6H2, 2,4,6-F3C6H2, 3,4,5-F3C6H2) have been prepared and isolated from the reactions of the mono-, di-, or tri-fluorophenol with BCl3. The Lewis acidity of these borates has been determined by NMR spectroscopic and theoretical methods and compared to their well-established borane counterpart. The dataset includes experimental procedures and compound characterisation. Reserch results based upon these data are published at https://doi.org/10.1039/D2DT04095F
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2023-01-26
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