A Lanthanide−Gallium Complex Stabilized by the N-Heterocyclic Carbene Group
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https://figshare.com/articles/dataset/A_Lanthanide_Gallium_Complex_Stabilized_by_the_N_Heterocyclic_Carbene_Group/3009853
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资源简介：
The complex [Nd(L‘){Ga(NArCH)2}(N‘ ‘)(THF)], which exhibits the first f-element−gallium bond, is formed from the reaction between the N-heterocyclic carbene-supported neodymium complex [Nd(L‘)(N‘ ‘)(I)] (L‘ = ButNCH2CH2{C(NCSiMe3 CHNBut)}; N‘ ‘ = N(SiMe3)2) and the anionic gallium(I) heterocycle [Ga(NArCH)2][K(tmeda)] (Ar = 2,6-Pri2C6H3). The Nd−Ga bond energy is calculated to be 386 kJ mol-1.
创建时间：
2016-02-29
