A Trimetallic Compound Containing Zn−Zr Bonds: Cp2Zr(ZnR)2 (Cp = C5H5; R = C6H3-2,6-(2,4,6-i-Pr3C6H2)2)
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https://figshare.com/articles/dataset/A_Trimetallic_Compound_Containing_Zn_Zr_Bonds_Cp_sub_2_sub_Zr_ZnR_sub_2_sub_Cp_C_sub_5_sub_H_sub_5_sub_R_C_sub_6_sub_H_sub_3_sub_-2_6-_2_4_6-_i_i_i_-Pr_sub_3_sub_C_sub_6_sub_H_sub_2_sub_sub_2_sub_/12077169
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资源简介：
m-Terphenylzinc iodides RZnI2Li(OEt2)2 (1) and RZnI (2) (R = C6H3-2,6-(2,4,6-i-Pr3C6H2)2) were prepared and structurally characterized. The sodium metal reduction of Cp2ZrCl2 with 2 afforded Cp2Zr(ZnR)2 (3) as the first structurally characterized compound containing a Zn−Zr bond. The nature of the unique Zn−Zr bond for 3 was further probed by DFT computations.
创建时间：
2007-06-04
