A Trimetallic Compound Containing Zn−Zr Bonds: Cp2Zr(ZnR)2 (Cp = C5H5; R = C6H3-2,6-(2,4,6-i-Pr3C6H2)2)
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资源简介：
m-Terphenylzinc iodides RZnI2Li(OEt2)2 (1) and RZnI (2) (R = C6H3-2,6-(2,4,6-i-Pr3C6H2)2) were prepared and structurally characterized. The sodium metal reduction of Cp2ZrCl2 with 2 afforded Cp2Zr(ZnR)2 (3) as the first structurally characterized compound containing a Zn−Zr bond. The nature of the unique Zn−Zr bond for 3 was further probed by DFT computations.
创建时间：
2007-06-04
