Template-Directed Synthesis of Nets Based upon Octahemioctahedral Cages That Encapsulate Catalytically Active Metalloporphyrins
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https://figshare.com/articles/dataset/Template_Directed_Synthesis_of_Nets_Based_upon_Octahemioctahedral_Cages_That_Encapsulate_Catalytically_Active_Metalloporphyrins/2558410
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资源简介：
meso-Tetra(N-methyl-4-pyridyl)porphine
tetratosylate (TMPyP) templates the synthesis of six new metal–organic
materials by the reaction of benzene-1,3,5-tricarboxylate with transition
metals, five of which exhibit HKUST-1 or tbo topology
(M = Fe, Mn, Co, Ni, Mg). The resulting materials, porph@MOMs, selectively encapsulate the corresponding metalloporphyrins in
octahemioctahedral cages and can serve as size-selective heterogeneous
catalysts for oxidation of olefins.
创建时间：
2016-02-22
