Rhodium-Catalyzed Azide–Alkyne Cycloaddition of Internal Ynamides: Regioselective Assembly of 5‑Amino-Triazoles under Mild Conditions
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https://figshare.com/articles/dataset/Rhodium-Catalyzed_Azide_Alkyne_Cycloaddition_of_Internal_Ynamides_Regioselective_Assembly_of_5_Amino-Triazoles_under_Mild_Conditions/5462230
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资源简介：
A rhodium-catalyzed
azide–alkyne cycloaddition of internal
ynamides is described. The reaction could be performed in a wide range
of solvents, including aqueous media, under mild conditions without
careful exclusion of air and moisture, giving a variety of 5-amino-triazoles
as a single regioisomer. The mechanism of regioselective cycloaddition
was rationalized by means of density functional theory calculations.
创建时间：
2017-10-02
