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Pressure-Responsive Curvature Change of a “Rigid” Geodesic Ligand in a (3,24)-Connected Mesoporous Metal–Organic Framework

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Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Pressure_Responsive_Curvature_Change_of_a_Rigid_Geodesic_Ligand_in_a_3_24_Connected_Mesoporous_Metal_Organic_Framework/2588893
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A (3,24)-connected mesoporous metal–organic framework, PCN-69, was synthesized by linking a hexatopic ligand btti with dicopper paddlewheel clusters. This material has rigid connectivity but a flexible framework, which has been attributed to a curvature change of the ligand.
创建时间:
2016-02-22
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