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Synthesis and Properties of Tribenzocarbazoles via an Acid-Promoted Retro (2+2)-Cycloaddition of Azapropellanes

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NIAID Data Ecosystem2026-03-10 收录
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https://figshare.com/articles/dataset/Synthesis_and_Properties_of_Tribenzocarbazoles_via_an_Acid-Promoted_Retro_2_2_-Cycloaddition_of_Azapropellanes/6473159
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We describe herein the development of a new method to synthesize tribenzocarbazoles via an acid-promoted retro (2+2)-cycloaddition of azapropellanes, which were prepared by potassium hexamethyldisilazide (KHMDS)-promoted (2+2)-cycloaddition. The tribenzocarbazoles showed strong fluorescence both in solution and the solid state. The structural, electronic, and optical properties of the synthetic tribenzocarbazoles are also described.
创建时间:
2018-06-10
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