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Aziridinofullerene: A Versatile Platform for Functionalized Fullerenes

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Aziridinofullerene_A_Versatile_Platform_for_Functionalized_Fullerenes/2688409
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An aziridine moiety on the fullerene core can serve as an acid-triggered reacting template for the controlled synthesis of a range of functionalized fullerenes that are otherwise difficult to synthesize in an efficient and selective manner. A copper-catalyzed aziridination of C60 for the practical synthesis of aziridinofullerene 1 and acid-catalyzed reactions of 1 with mono- and bifunctional nucleophiles as well as alkynes are described. The rapid generation of structural diversity in a single chemical operation using the common platform 1 is notable.
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2016-02-23
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