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Palladium-Catalyzed Regioselective C8–H Amination of 1‑Naphthylamine Derivatives with Aliphatic Amines

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Figshare2016-09-12 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Palladium-Catalyzed_Regioselective_C8_H_Amination_of_1_Naphthylamine_Derivatives_with_Aliphatic_Amines/3799284
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A simple and facile protocol for palladium-catalyzed picolinamide-directed C8–H amination of 1-naphthylamine derivatives with simple secondary aliphatic amines was developed, thereby providing a new route to 1,8-naphthalenediamine derivatives. It is noteworthy that the picolinamide moiety as a bidentate directing group may play a key role in this regioselective transformation.
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2016-09-12
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